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In n = 1 RPP, the BA cations interlaced with one another due to the interaction with apical I atom (shaded as red) of floor PbI6 octahedron, where a larger in-aircraft octahedral tilt and a small out-of-airplane tilt exist. In the case of n = 4 RPP, the BA molecules undertake a “head-to-head” configuration so that their NH3 teams are po